The mechanism of activation and nonequilibrium distribution functions in unimolecular reactions
β Scribed by E. E. Nikitin
- Book ID
- 112362249
- Publisher
- Springer
- Year
- 1967
- Tongue
- English
- Weight
- 378 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0040-5760
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π SIMILAR VOLUMES
## Abstract A new formulation of the Lindemann mechanism of unimolecular reactions in gaseous phase is presented, without the use of steady state hypothesis. It is hereby shown that the nature of applicability of steady state hypothesis in the regime of high reactant gas pressure is different from
The effective energy distribution of activated molecules at the time of reaction under soft collision conditions f ' ( E , w ) is pressure dependent and therefore difficult to recover from unimolecular decomposition data obtained a t different pressures. We show in this work that the part of this fu