The recent report of the alkylation and subsequent debromination of bis(tribromomethy1) sulfone,2i, with trivalent phosphorus reagents provides an elegant route to dialkyl thiirene dioxides and thus to dialkyl acetylenes.
The addition of bis-carbomethoxycarbene to olefins
โ Scribed by Maitland Jones Jr.; Anthony Kulczycki Jr.; Karl F. Hummel
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 207 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The free radical addition of TFE and HFP to hydroxyl ended p-THF and p-ethyleneglycol (PEG) will be described. Under the reaction conditions the fluoro-olefins react with the hydroxyl groups of PEG but not with those of p-THF. The reason for this interesting difference and the products resulting fro
## Abstract The addition of methoxy radicals to several olefins has been studied by a competitive method at 127ยฐC in gas phase. The thermal decomposition of dimethyl peroxide was used as methoxy radical source. The rate of addition to the double bond was measured relative to the oxidation of carbon