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“Selenosulfonation”: The addition of selenosulfonates to olefins

✍ Scribed by Thomas G. Back; Scott Collins

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
36 KB
Volume
22
Category
Article
ISSN
0040-4039

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The title compounds were synthesized from a readily available steroidal acetylene by a protocol employing selenosulfonation, introduction of the appropriate side chain at C-24 via an alkyl selenocuprate, and reductive desulfonylation. A similar elimination has been observed in the reaction of the s