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THE ADDITION COMPOUNDS OF ALDEHYDES AND KETONES WITH ORGANIC ACIDS.

โœ Scribed by Kendall, James; Gibbons, Willis A.


Book ID
126922871
Publisher
American Chemical Society
Year
1915
Tongue
English
Weight
741 KB
Volume
37
Category
Article
ISSN
0002-7863

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Lewis acid-promoted addition of methylen
โœ Katsukiyo Miura; Mizuki Takasumi; Takeshi Hondo; Hiroshi Saito; Akira Hosomi ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 242 KB

In the presence of TiCi4, me~ylenecyclopropane (la) easily reacted with Jdln~u~tlc aldehydes to give the p-(chiorome~yl)allylate~ products 2 in good yields along with a small amount of the methylenetetrahydrofurans 3. The reacti~ with chiral a-and ~-alkoxy aldehydes lwoceeded with high levels of cl~