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Enthalpies of addition of radicals to aldehydes, ketones, acids and esters

โœ Scribed by Borisov, I. M. ;Mikhaylov, D. A. ;Khursan, S. L.

Publisher
Springer
Year
1999
Tongue
English
Weight
196 KB
Volume
68
Category
Article
ISSN
0133-1736

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โœ Katsukiyo Miura; Mizuki Takasumi; Takeshi Hondo; Hiroshi Saito; Akira Hosomi ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 242 KB

In the presence of TiCi4, me~ylenecyclopropane (la) easily reacted with Jdln~u~tlc aldehydes to give the p-(chiorome~yl)allylate~ products 2 in good yields along with a small amount of the methylenetetrahydrofurans 3. The reacti~ with chiral a-and ~-alkoxy aldehydes lwoceeded with high levels of cl~