The adamantane rearrangement of syn- and anti-Tricyclo[4.2.1.1.12,5] decane. Part II. Rearrangements initiated by regioselective formation of carbocations at C(3) and C(9)
✍ Scribed by Marco Brossi; Camille Ganter
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- German
- Weight
- 719 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
For Part I, see [I]. Present address: Ciba-Geigy AG,
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## Abstract The behaviour of the regioselectively generated carbocation centers at C(2) and C(6) in 1,2‐trimethylenenorbornanes was investigated in order to study the occurrence or absence of a degenerate rearrangement **E⇄M** in the adamantane rearrangement of both 1,2‐__endo__‐ (**1**) and 1,2‐__
## Abstract In view of the significance of steric compression in the base‐catalyzed intramolecular cyclization of polycyclic olefinic alcohols, the standard enthalpies of formation of __anti__^9,10^‐10 __endo__‐hydroxytricyclo [4.2.1.1^2,5^]deca‐3,7‐dien‐9‐one **(1)** and 9‐oxatetracyclo [5.4.0.0^3