## Abstract The two novel tricyclic C~10~H~16~ compounds __anti__‐ and __syn__‐tricyclo [4.2.1.1^2,5^]‐ decane (**16** and **17**, respectively) were synthesized starting either from the photodimer **2** (__anti__) or the two cycloaddition products **8** (__anti__) and **9** (__syn__).
The Aluminum-Bromide-Catalyzed Adamantane Rearrangement of syn- and anti-Tricyclo[4.2.1.12,5]decane
✍ Scribed by Marco Brossi; Camille Ganter
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- German
- Weight
- 194 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0018-019X
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📜 SIMILAR VOLUMES
Regioselective generation of the C(2)-carbocation a of tricyc10[4.2.2.0',~]decane (1) by treatment of both corresponding epimeric alcohols 5 and 6 with BF, and trapping the rearranged tricy~lo[S.3.0.O~~~]decan-7-yl carhocation b with Et,SiH as hydride-ion donor (ionic hydrogenation) gives the corres
## Abstract Acid treatment of 9__exo__‐methyl‐__anti__^10,11^‐tricyclo[4.2.1.1^2,5^]deca‐3,7‐diene‐9__endo__, 10__endo__‐diol (**8**) leads to the two isomeric pentacyclic ethers **7** and **9** by intramolecular nucleophilic substitution of a protonated OH‐group with participation of a C,C‐double