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The Adamantane Rearrangement of 1,2-Trimethylenenorbornanes. III. AlBr3-catalyzed rearrangement to 2,6-trimethylenenorbornane

✍ Scribed by Alfred Michael Klester; Camille Ganter

Publisher: John Wiley and Sons
Year: 1983
Tongue: German
Weight: 483 KB
Volume: 66
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19830660422

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✦ Synopsis

Abstract

From treatment of D‐labelled 1, 2__exo__‐, 1, 2__endo__‐ and 2__endo__, 6__endo__‐trimethylene‐norbornane (1, 2 and 3, resp.) with aluminum bromide in carbon disulfide, the evidence is gained that a degenerate rearrangement is involved in the admantane rearrangement of both 1 and 2 to 3.

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