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The adamantane rearrangement of 1,2-trimethylenenorbornanes. Part IV. Hydride-ion abstraction in 1,2-exo-trimethylenenorbornane

✍ Scribed by Alfred Michael Klester; Camille Ganter

Publisher
John Wiley and Sons
Year
1985
Tongue
German
Weight
371 KB
Volume
68
Category
Article
ISSN
0018-019X

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✦ Synopsis

4, 'Adamantaneland': a set of 19 isomeric C,,H,,-hydrocarbons [2-4]. Compounds 4 6 correspond to the general formula B D (R' = D, R2 = R3 = R4 = H) of Scheme 3 in [I]. ' 1 k , h = log ([Alt/[AlJ/log ([BIJBIJ or kA/k, = {log[(lxt)/(lxo)] + log([ -s)}/{log(x,/x,) f log(1 -s)), where xO and x, represent percentage of Bjl00, and s represents percentage of conversion/100 [5].

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