The first excited triplet state of dimesitylcarbene has been generated in solution at room temperature. It has a lifetime of 60 ns and shows fluorescence with A mp~ = 501 nm and absorption with A,,. = 360 nm. This species is quenched by oxygen and carbon tetrachloride with rate constants of (4.4kO.8
The absorption spectrum and reactivity of excited triplet state diphenylcarbene
โ Scribed by Keith A. Horn; Bruce D. Allison
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 450 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0009-2614
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