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The electronic structure of actinyl ions: the excited-state absorption spectrum of Cs2UO2Cl4

✍ Scribed by R.G. Denning; I.D. Morrison

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 356 KB
Volume: 180
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)87123-s

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✦ Synopsis

The polarised excited-state optical absorption spectrum of a single crystal of Cs$JOzC14 at 77 K is reported. The intense absorption band near 580 nm is polarised parallel to the U-O axis. This observation is used to locate the highest-filled gerade orbital and to establish the role of the 6d orbitals in the formation of the uranyl ion.

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