Incorporation studies using [I ,2-13Cz]acetate into a novel sterpurene sesquitetpene, 9,12-dihydroxysrerpurene (I), have allowed the absolute stereochemistry of the emymic cyclisation offarnesyl pyrophsphate to sterpurene to be elucidated. Observation of two-bond 13C-13C coupling across the cyclobut
The absolute configuration of the sterpurene sesquiterpenes
β Scribed by Chris Abell; Andrew P. Leech
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 147 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
&nmgcy: The ahsotute arnttguratbn of the stsrpurene sesquiterpenes tsotated from Sferwumpurpumum has heen determined both hy the use of the excttcn chirattty methcd on (2). a dedvattve of 7,12dihydroxy-
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