The absolute configuration of the axane sesquiterpenes from the sponge axinella cannabina
β Scribed by M. Adinolfi; L. De Napoli; B. Di Blasio; A. Iengo; C. Pedone; C. Santacroce
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 74 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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&nmgcy: The ahsotute arnttguratbn of the stsrpurene sesquiterpenes tsotated from Sferwumpurpumum has heen determined both hy the use of the excttcn chirattty methcd on (2). a dedvattve of 7,12dihydroxy-
The absolute configuration of halisulfate 3 (1), a metabolite of the sponge Ircinia sp. from the Philippines, was determined in two steps. The (13S) absolute configuration was derived by application of the chiral amide method using acid 5. The (8R.9S) stereochemistry of the bicyclic ring system was