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The 3Σ+g (4 3P, 4 3P) ↔ 3Σ+u (4 3P, 4 1S) vibronic spectrum of Zn2

✍ Scribed by W. Kedzierski; J.B. Atkinson; L. Krause

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
245 KB
Volume
222
Category
Article
ISSN
0009-2614

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✦ Synopsis

The spectroscopy of the %~( 4 3P, 4 'P) state in Zn2 was studied by pump and probe methods with time resolution. Structured excitation and fluorescence spectra that were observed in the 266-277 nm region, are assigned as due to 3Xl(4 3P, 4 'P)a: (4 "P, 4 'S) vibronic transitions. Vibrational analysis of the spectra yielded the vibrational frequencies, relative energies, and relative equilibrium internuclear separations for the two states.

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