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Perturbation on intensity profiles of the CO 4pσ K 1Σ+3sσ B 1Σ+ (00) and 4pπ L 1Π3sσ B 1Σ+ (00) bands

✍ Scribed by Shigeyuki Sekine; Chiaki Hirose

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
368 KB
Volume
212
Category
Article
ISSN
0009-2614

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✦ Synopsis

The 4po K 'E+-~so B %+(0-O) and 4pn L 'Il-3so B 'X+ (O-O) bands of carbon monoxide were re-cxamined by the optogalvanic method. We found that the intensity ofthe rotational lines was proportional to the laser power up to about lo9 W cm2 and that the band profiles were affected by the Cuncoupling interaction among the rotational levels of the 4pa L 'II( u=O), the 4po K'X+(v=O), and an unidentified 'Z+ state. The 3pn C 'C+(v=5 or 6) state which is higher than the 4pr L 'TI(v=O) state by less than 200 cm-' was proposed as a likely candidate for the unidentified state.

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