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Laser-induced fluorescence from the 3Πu (4 3P, 4 3P) state of Zn2

✍ Scribed by W. Kedzierski; J.B. Atkinson; L. Krause

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
244 KB
Volume
215
Category
Article
ISSN
0009-2614

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✦ Synopsis

The 'l&(4 3P, 4 3P) state of the Znz excimer was excited by pump-and-probe irradiation of Zn vapor in a quartz cell. The resulting structured fluorescence and excitation spectra, which were recorded in the 270-290 nm spectral region, are interpreted as arising from 'lIy(4 'P, 4 'P)-'l&(4 'P, 4 'S) vibronic transitions. An analysis of the vibrational structures yielded the vibrational frequencies, relative energies, and relative equilibrium internuclear separations for the 'II. and 'II, states.

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