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The 3,4-dimethoxybenzyl group: A protective group for new 2-imino-imidazolidine derivates

✍ Scribed by D. Huber; G. Leclerc; J.D. Ehrhardt; G. Andermann


Book ID
104228180
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
222 KB
Volume
28
Category
Article
ISSN
0040-4039

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Selective hydrogenolysis of the benzyl p
✍ Yuji Oikawa; Tatsuyoshi Tanaka; Kiyoshi Horita; Osamu Yonemitsu πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 201 KB

The benzyl protecting group for hydroxy function was selectively removed by catalytic hydrogenolysis with Raney nickel in the presence of the MPM (4-methoxybenzyl) and DMPM (3,4-dimethoxybenzyl)protecting groups, and applied to the synthesis of some synthons to macrolide and polyether antibiotics.