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The (3000), (4000) and (5000) stretching overtone bands of silane—II. The rotational analysis in a normal-mode picture

✍ Scribed by Qingshi Zhu; Hui Ma; Baoshu Zhang; Yueren Ma; Haibo Qian


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
560 KB
Volume
46
Category
Article
ISSN
1386-1425

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Local-mode rotational structures in the
✍ Qingshi Zhu; Baoshu Zhang; Yueren Ma; Haibo Qian 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 285 KB

The (3000) and ( ) stretching overtone bands of silane, SiH.,, have been observed near 6362 and IO268 cm-' by Fourier transfer spectroscopy with a resolution of 0.01 cm-'. In both spectra the pseudo-symmetric-top rotational structure, similar to that observed in the (3000) band of germane, was clear