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The (3000), (4000) and (5000) stretching overtone bands of silane—I. The effect of local-mode vibration on rotational constants

✍ Scribed by Qingshi Zhu; Baoshu Zhang; Yueren Ma; Haibo Qian

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 429 KB
Volume: 46
Category: Article
ISSN: 1386-1425
DOI: 10.1016/0584-8539(90)80198-8

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The (3000) and ( ) stretching overtone bands of silane, SiH.,, have been observed near 6362 and IO268 cm-' by Fourier transfer spectroscopy with a resolution of 0.01 cm-'. In both spectra the pseudo-symmetric-top rotational structure, similar to that observed in the (3000) band of germane, was clear

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