The 17α-hydroxylation of cardenolides. Conversion of the cardenolideto the cortisone side-chain

✍ Scribed by N. Danieli; Y. Mazur; F. Sondheimer

• Publisher: Elsevier Science
• Year: 1967
• Tongue: French
• Weight: 42 KB
• Volume: 23
• Category: Article
• ISSN: 0040-4020
• DOI: 10.1016/s0040-4020(01)83379-2

✦ Synopsis

THE 17a-HYDROXYLATION OF CARDENOLIDES. CONVERSION OF THE CARDENOLIDE TO THE CORTISONE SIDE-CHAIN. N. DANIELI, Y. MAZUR and F. SONDHEIMER. Tetrahedron 23,715 (1967).

The [aIn value of 17a-hydroxydigitoxigenin acetate (II) should be -14" @OH) instead of + 155" (EtOH).