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The 17α-hydroxylation of cardenolides : Conversion of the cardenolide to the cortisone side-chain

✍ Scribed by N. Danieli; Y. Mazur; F. Sondheimer

Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
404 KB
Volume
23
Category
Article
ISSN
0040-4020

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The 17α-hydroxylation of cardenolides. C
The 17α-hydroxylation of cardenolides. Conversion of the cardenolideto the cortisone side-chain
✍ N. Danieli; Y. Mazur; F. Sondheimer 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 42 KB

THE 17a-HYDROXYLATION OF CARDENOLIDES. CONVERSION OF THE CARDENOLIDE TO THE CORTISONE SIDE-CHAIN. N. DANIELI, Y. MAZUR and F. SONDHEIMER. Tetrahedron 23,715 (1967). The [aIn value of 17a-hydroxydigitoxigenin acetate (II) should be -14" @OH) instead of + 155" (EtOH).

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ChemInform Abstract: A New Approach to the Synthesis of the 17β-Butenolide Fragment of Cardenolides.
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