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Tetrathiafulvalene; Naphthochinon-(1,2)-[(1,3)-dithiol-(2)-methid]-Tetracyano-chinodimethan-Komplexe

✍ Scribed by Egon Fanghänel; Wolfgang John; Helmut Fricke; Gottfried Kempe

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
276 KB
Volume
18
Category
Article
ISSN
0044-2402

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Reacting 2-lithio-1,3-dithioles with 1,3-dithiolium salts results in formation of both symmetrical and unsymmetrical tetrathiafulvalenes. The symmetrical tetra-thiafulvalenes are probably formed via a carbene intermediate which is generated by loss of an hydride from the 2-lithio-1,3dithioles.