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Tetraphenol-based diphosphite ligands: synthesis, characterization, and application in the rhodium-catalyzed hydroformylation of octenes

✍ Scribed by Michèle Janssen; Laura Bini; Bart Hamers; Christian Müller; Dieter Hess; Andrea Christiansen; Robert Franke; Dieter Vogt


Book ID
104097471
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
333 KB
Volume
51
Category
Article
ISSN
0040-4039

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## Abstract The synthesis of calix[4]arene‐based phosphorus diamides and phosphites is described. These oligocyclic ligands have been tested in the Rh(I)‐ catalyzed hydroformylation of 1‐octene. Depending on the reaction conditions, yields up to 99% and __n/iso__‐selectivities between 0.7 and 2.6 h