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Synthesis, Characterization ofN-Pyrrolylphosphanes Based on Heterocyclic Amine Backbones and Their Application in Hydroformylation of 1-Octene

โœ Scribed by Zhang, Lin; Li, Chun; Zheng, Xueli; Fu, Haiyan; Chen, Hua; Li, Ruixiang


Book ID
125357529
Publisher
Springer US
Year
2014
Tongue
English
Weight
317 KB
Volume
144
Category
Article
ISSN
1011-372X

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## Abstract The synthesis of calix[4]areneโ€based phosphorus diamides and phosphites is described. These oligocyclic ligands have been tested in the Rh(I)โ€ catalyzed hydroformylation of 1โ€octene. Depending on the reaction conditions, yields up to 99% and __n/iso__โ€selectivities between 0.7 and 2.6 h