The title compound, [Zn 2 (C 7 H 5 O 2 ) 4 (C 10 H 14 N 2 O) 2 ], has a centrosymmetric dimeric molecule with four symmetrical benzoate bridges and two axial nitrogen-base ligands. The ZnÁ Á ÁZn separation of 2.8860 (4) A Ê does not represent a formal direct metal±metal bond. Coordination of zinc is
Tetrakis(μ-benzoato-O:O')bis(N,N-diethylnicotinamide-N')dicopper(II)
✍ Scribed by Hökelek, T. ;Necefouglu, H. ;Balcı, M.
- Book ID
- 114511880
- Publisher
- International Union of Crystallography
- Year
- 1995
- Tongue
- English
- Weight
- 420 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
The bis(4-ethylpyridine) adduct of dicopper(II) tetrabenzoate, [ Cu 2 (C 7 H 5 O 2 ) 4 (C 7 H 9 N) 2 ], has centrosymmetrically related square-pyramidal Cu atoms bridged by four benzoate ions; the heterocyclic ligands that occupy the apical sites are disordered.
The title dinuclear Co II complex, [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 -(H 2 O)], has C 2 symmetry with the coordinated water O atom located on a twofold axis. Two Co II ions are bridged by two methylbenzoate (MBZ) anions and one water molecule. Each Co II ion displays a distorted octahedral co