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Tetrakis(μ-6-ammonio­hexanoato-1κO:2κO′)­bis­[chloro­copper(II)] dichloride tetrahydrate

✍ Scribed by Lah, Nina ;Leban, Ivan

Book ID
104483893
Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
161 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Cu 2 (C 6 H 13 NO 2 ) 4 Cl 2 ]Cl 2 Á4H 2 O, has a centrosymmetric, dimeric and dicationic tetracarboxylatodicopper(II) core with apical positions occupied by chloride. The positive charge is balanced by two non-coordinating chlorides that, together with four uncoordinated water molecules per dimeric unit, are involved in extensive hydrogen bonding, leading to a cohesive crystal structure.

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