✦ LIBER ✦

Tetrakis(triphenylarsine)silver(I) hexafluorophosphate

✍ Scribed by Meijboom, Reinout ;Janse van Rensburg, J. Marthinus ;Kirsten, Leo ;Viljoen, J. Augustinus

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 171 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806036373

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, [Ag(AsC 18 H 15 ) 4 ]PF 6 , crystallizes with the cation on a threefold rotation axis and the anions on positions with site symmetry 3. The Ag atom is surrounded by four arsine ligands forming a distorted tetrahedral configuration. The Ag-As distances are 2.6381 (6) and 2.6499 (9) A ˚, and the As-Ag-As angles are 108.91 (1) and 110.03 (1) .

📜 SIMILAR VOLUMES

Tetrakis(tri-p-tolylphosphine-κP)silve

Tetrakis(tri-p-tolylphosphine-κP)silver(I) hexafluorophosphate

✍ Venter, Gertruida J. S. ;Meijboom, Reinout ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 160 KB

Single-crystal X-ray study T = 295 K Mean (C-C) = 0.007 A R factor = 0.038 wR factor = 0.102 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

catena-Poly[[(tetrafluoroborato-κF)sil

catena-Poly[[(tetrafluoroborato-κF)silver(I)]-μ-triphenylphosphine-κ2P:C3]

✍ Brayshaw, Simon K. ;Molinos, Eduardo ;Weller, Andrew S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 250 KB

Redetermination of catena-poly[[[bis(et

Redetermination of catena-poly[[[bis(ethylenediamine)platinum(II)]-μ-chloro-[bis(ethylenediamine)platinum(IV)]-μ-chloro] tetrakis(hexafluorophosphate)]

✍ Matsushita, Nobuyuki 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 277 KB

Redetermination of catena-poly[[[bis(ethylenediamine)platinum(II)]-l-chloro-[bis(ethylenediamine)platinum(IV)]-l-chloro] tetrakis-(hexafluorophosphate)]

Phyllo-poly[[silver(I)-di-μ2-4-aminomet

Phyllo-poly[[silver(I)-di-μ2-4-aminomethylpyridine-κ2N:N′] hexafluorophosphate]: a two-dimensional coordination polymer formed by the reaction of silver(I) hexafluorophosphate with 4-aminomethylpyridine

✍ Feazell, Rodney P. ;Carson, Cody E. ;Klausmeyer, Kevin K. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 368 KB

(p-Toluenesulfonato)tris(triphenylars

(p-Toluenesulfonato)tris(triphenylarsine)silver(I)

✍ Meijboom, Reinout ;Janse van Rensburg, J. Marthinus ;Senekal, Nadine D. ;Venter, 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 161 KB

Acetatotris(triphenylarsine)silver(I) ac

Acetatotris(triphenylarsine)silver(I) acetonitrile solvate monohydrate

✍ Meijboom, Reinout ;Muller, Alfred 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 877 KB

In the title compound, [Ag(C 2 H 3 O 2 )(C 18 H 15 As) 3 ]ÁC 2 H 3 NÁ-H 2 O, the Ag atom is coordinated by three arsine ligands and one O atom, forming a distorted tetrahedral configuration. The Ag-As bond distances are 2.5921 (6), 2.6190 (8) and 2.6373 (9) A ˚, and the Ag-O bond distance is 2.3269

Tetra­kis(triphenyl­arsine)silver(I) hexa­fluoro­phosphate

✦ Synopsis

Tetrakis(triphenylarsine)silver(I) hexafluorophosphate