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Acetatotris(triphenylarsine)silver(I) acetonitrile solvate monohydrate

✍ Scribed by Meijboom, Reinout ;Muller, Alfred

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
877 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Ag(C 2 H 3 O 2 )(C 18 H 15 As) 3 ]ÁC 2 H 3 NÁ-H 2 O, the Ag atom is coordinated by three arsine ligands and one O atom, forming a distorted tetrahedral configuration. The Ag-As bond distances are 2.5921 (6), 2.6190 (8) and 2.6373 (9) A ˚, and the Ag-O bond distance is 2.3269 (18) A ˚. The Ag atom is displaced 0.7781 (3) A ˚out of the plane defined by the three As atoms.

Related literature

The crystal structure of the highly related complex [Ag(4-MeC 6 H 4 SO 3 )(AsPh 3 ) 3 ] has already been published (Meijboom,

📜 SIMILAR VOLUMES

(2-Amino-3,5-dimethylbenzenesulfonato-κN
(2-Amino-3,5-dimethylbenzenesulfonato-κN)bis(triphenylphosphine-κP)silver(I) acetonitrile solvate
✍ Han, Jia-Jun ;Li, Ning 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 838 KB

The title compound, [Ag(C~8~H~10~NO~3~S)(C~18~H~15~P)~2~]·CH~3~CN, has a mononuclear structure, where the Ag^I^ cation is three-coordinated by two triphenylphosphine ligands and one N atom from the 2-amino-3,5-dimethylbenzenesulfonate anion in a distorted trigonal-planar AgP~2~N arrangement. A netwo