The structure of the title compound, [Zn(C 92 H 60 N 4 )-(C 2 H 3 N)]ÁC 2 H 3 N, shows relatively small saddle-type distortion with ruf¯ing, compared to other dodecaphenylporphyrin complexes.
(Acetonitrile-κN)(4′-phenyl-2,2′:6′,2′′-terpyridine-κ3N)silver(I) hexafluorophosphate acetonitrile solvate
✍ Scribed by Hou, Lei ;Li, Dan ;Yin, Ye-Gao ;Wu, Tao ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 179 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.023 A Ê R factor = 0.061 wR factor = 0.161 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Cu 2 I 2 (C 12 H 8 N 2 ) 2 ]ÁC 2 H 3 N, two Cu I atoms are bridged by two I atoms and each Cu I atom is chelated by a 1,10-phenanthroline ligand to give four-coordinate tetrahedral geometry.
Acetonitrile-jN)(2,2 0 0 0 :6 0 0 0 ,2 0 0 00 0 0 -terpyridylj 3 N)palladium(II)] bis(hexafluorophosphate)