Tetrakis(phenylthiourea-κS)copper(I) chloride
✍ Scribed by Liu, Yu ;Xu, Duan-Jun
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 241 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Molecules of the title compound, [HgI 2 (C 14 H 11 ClN 2 OS) 2 ], are discrete and have crystallographic twofold rotation symmetry, with the Hg atom in a four-coordinate environment. The geometry of the central Hg atom is distorted tetrahedral with bond angles in the range 99.00 (8)±137.56 (3) .
The crystal structure of the title compound, [Cu(C 2 H 3 S 2 )-(C 18 H 15 P) 2 ]Á1.5C 7 H 8 , is reported. The compound is monomeric with the copper metal atom assuming a distorted tetrahedral geometry.
The molecule of the title compound, [Cu~4~I~4~(C~18~H~21~P)~4~], which lies on a crystallographic twofold rotation axis, displays a cubane-like Cu~4~I~4~ core.
The title compound, [Cu(C 5 H 9 N) 4 ]ClÁH 2 O, was obtained from the reaction of copper(II) chloride hydrate with KCN in the presence of two equivalents of tert-butylisocyanide. The reaction proceeds via the reduction of copper and the formation of (CN) 2 . The compound shows a tetrahedrally surrou