Tetrakis(dimethylammonium) hexachlorotungstate(III) chloride
✍ Scribed by Xu, Wei ;Lin, Jian-Li
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 186 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, (C~2~H~8~N)~4~[WCl~6~]Cl, contains discrete [WCl~6~]^3−^ and Cl^−^ anions and dimethylammonium cations. Both anions lie on crystallographic twofold rotation axes. N—H...Cl hydrogen-bond interactions result in the formation of {[(CH~3~)~2~NH~2~]~2~(WCl~6~)}^−^ anionic layers and [(CH~3~)~2~NH~2~]~2~Cl^+^ cationic units.
📜 SIMILAR VOLUMES
The title coordination compound, (C 8 H 20 N)[Co(C 30 H 16 -N 4 O 4 S 4 ) 2 ]Cl, was formed on aerobic oxidation of a reaction mixture containing the doubly deprotonated N-(benzo[d]thiazol-2-ylmethyl)-2-mercaptobenzamide ligand and CoCl 2 in a 2:1 ratio. Aerobic conditions were employed to oxidize t