𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Tetra­kis(dimethyl­ammonium) hexachlorotungstate(III) chloride

✍ Scribed by Xu, Wei ;Lin, Jian-Li


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
186 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


The title compound, (C~2~H~8~N)~4~[WCl~6~]Cl, contains discrete [WCl~6~]^3−^ and Cl^−^ anions and dimethylammonium cations. Both anions lie on crystallographic twofold rotation axes. N—H...Cl hydrogen-bond interactions result in the formation of {[(CH~3~)~2~NH~2~]~2~(WCl~6~)}^−^ anionic layers and [(CH~3~)~2~NH~2~]~2~Cl^+^ cationic units.


📜 SIMILAR VOLUMES


Bis(tetra­ethyl­ammonium) bis­[N-(2-merc
✍ Frome, Michelle J. ;Cooper, Lisa E. ;Lewis, Breia J. ;Ferguson, Michael J. ;Dale 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 198 KB

The title coordination compound, (C 8 H 20 N)[Co(C 30 H 16 -N 4 O 4 S 4 ) 2 ]Cl, was formed on aerobic oxidation of a reaction mixture containing the doubly deprotonated N-(benzo[d]thiazol-2-ylmethyl)-2-mercaptobenzamide ligand and CoCl 2 in a 2:1 ratio. Aerobic conditions were employed to oxidize t