The crystal structure of the centrosymmetric title compound, C 24 H 48 N 4 O 8 4+ Á4Cl À Á8H 2 O, consists of a 14-membered methylsubstituted C 10 N 4 cationic ring which interacts with the chloride ions and water molecules of crystallization to give a three-dimensional hydrogen-bonded network struc
Tetrakis(1,10-phenanthrolinium) hexachloridoeuropate(III) chloride
✍ Scribed by Clegg, William ;Harrington, Ross W.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 255 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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Tetrakis(l-4-chlorobenzoato)bis[(4-chlorobenzoato)(1,10-phenanthroline)dysprosium(III)]
The title compound, (C~2~H~8~N)~4~[WCl~6~]Cl, contains discrete [WCl~6~]^3−^ and Cl^−^ anions and dimethylammonium cations. Both anions lie on crystallographic twofold rotation axes. N—H...Cl hydrogen-bond interactions result in the formation of {[(CH~3~)~2~NH~2~]~2~(WCl~6~)}^−^ anionic layers and [
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The title complex, [Yb~2~(C~12~H~9~O~2~)~6~(C~12~H~8~N~2~)~2~], has a centre of symmetry. The nine-coordinate Yb^III^ atom has a distorted monocapped square antiprismatic geometry. Molecules are linked into three chains by C—H...O hydrogen bonds and π–π stacking interactions [centroid-to-centroid di