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Tetrakis(μ-naphthalene-1-acetato)bis[(naphthalene-1-acetato)(1,10-phenanthroline)ytterbium(III)]

✍ Scribed by Xia, Hai-Tao ;Liu, Yu-Fen ;Wang, Da-Qi ;Yang, Shu-Ping


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
1014 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title complex, [Yb~2~(C~12~H~9~O~2~)~6~(C~12~H~8~N~2~)~2~], has a centre of symmetry. The nine-coordinate Yb^III^ atom has a distorted monocapped square antiprismatic geometry. Molecules are linked into three chains by C—H...O hydrogen bonds and π–π stacking interactions [centroid-to-centroid distance 3.775 (4) Å]; combination of the three chains results in the formation of a three-dimensional network.


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In the title compound, [Pb~2~(C~12~H~6~O~4~)~2~(C~12~H~8~N~2~)]~__n__~ or [Pb~2~(1,4-NDC)~2~(__L__)]~__n__~, where 1,4-NDC is naphthalene-1,4-dicarboxylate and __L__ is 1,10-phenanthroline, the 1,4-NDC ligands link the Pb^II^ atoms into a layer structure. One Pb atom is ligated by __L__ and also bon