Molecules of the title complex, [SmTb(C~12~H~9~O~2~)~6~(C~12~H~8~N~2~)~2~]·2C~3~H~7~NO, are centrosymmetric with equal disorder of the Sm and Tb atoms. Each Sm^III^ and Tb^III^ ion is nine-coordinate. The Sm and Tb atoms have a distorted monocapped square-antiprismatic coordination geometry. The mol
Tetrakis(μ-naphthalene-1-acetato)bis[(naphthalene-1-acetato)(1,10-phenanthroline)ytterbium(III)]
✍ Scribed by Xia, Hai-Tao ;Liu, Yu-Fen ;Wang, Da-Qi ;Yang, Shu-Ping
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 1014 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title complex, [Yb~2~(C~12~H~9~O~2~)~6~(C~12~H~8~N~2~)~2~], has a centre of symmetry. The nine-coordinate Yb^III^ atom has a distorted monocapped square antiprismatic geometry. Molecules are linked into three chains by C—H...O hydrogen bonds and π–π stacking interactions [centroid-to-centroid distance 3.775 (4) Å]; combination of the three chains results in the formation of a three-dimensional network.
📜 SIMILAR VOLUMES
In the title compound, [Pb~2~(C~12~H~6~O~4~)~2~(C~12~H~8~N~2~)]~__n__~ or [Pb~2~(1,4-NDC)~2~(__L__)]~__n__~, where 1,4-NDC is naphthalene-1,4-dicarboxylate and __L__ is 1,10-phenanthroline, the 1,4-NDC ligands link the Pb^II^ atoms into a layer structure. One Pb atom is ligated by __L__ and also bon