Tetrakis[1-tert-butyl-1H-imidazole-2(3H)-thione-κS]palladium(II) dichloride dichloromethane disolvate
✍ Scribed by Wang, Yu-Ling ;Bi, Wen-Hua ;Li, Xing ;Cao, Rong
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 271 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, [Pd(C 7 H 12 N 2 ) 4 ]Cl 2 Á2CH 2 Cl 2 , the Pd atom lies on an inversion center and has a square-planar coordination involving the S atoms of the four 1-tert-butylimidazoline-2(3H)-thione ligands. The two chloride ions are not involved in coordination, but are engaged in hydrogen bonding.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 273 K Mean '(C±C) = 0.014 A Ê R factor = 0.052 wR factor = 0.113 Data-to-parameter ratio = 20.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.005 A Ê R factor = 0.031 wR factor = 0.080 Data-to-parameter ratio = 20.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.