The title compound, [NiCl 2 (C 11 H 14 N 2 O) 2 ], was synthesized from 1-(2-ethoxyethyl)benzimidazole and nickel dichloride in ethanol and is isostructural with its cobalt analogue. It shows a distorted tetrahedral geometry about Ni II , involving two Cl atoms and two benzimidazole N atoms. The cry
Bis[μ-2,2′-(butane-1,4-diyl)di-1H-benzimidazole-κ2N3:N3′]bis[diacetatocobalt(II)] ethanol disolvate
✍ Scribed by Ye, Ling
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 169 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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metal-organic papers m1222 Sevim Tu È rktekin et al. [CoCl 2 (C 11 H 14 N 2 O) 2 ] Acta Cryst. (2004). E60, m1220±m1222
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.006 A Ê R factor = 0.046 wR factor = 0.091 Data-to-parameter ratio = 16.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.003 A Ê R factor = 0.028 wR factor = 0.074 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, H 2 O 4 )(C 7 H 6 N 2 ) 2 (H 2 O) 2 ] n , is a one-dimensional polymeric complex bridged by fumarate dianions. The Ni atom lies on one inversion centre and the fumarate on another. The molecular chains are linked by hydrogen bonding. %±% stacking between parallel benzimidazole ri