Tetrahedral Clusters of GaMo4S8-Type Compounds: A Metal Bonding Analysis
β Scribed by A. Le Beuze; H. Loirat; M.C. Zerrouki; R. Lissillour
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 440 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0022-4596
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π SIMILAR VOLUMES
New tetrahedral metal cluster compounds were synthesized and characterized by means of single crystal Xray methods. GeV 4 S 8 (F43m, Z = 4, a = 9.655(1) A Γ ) and GeV 4 S 8 (a = 10.139(1) A Γ ) crystallize in the GaMo 4 S 8 -structure, built up by cubane-like (V 4 S 4 ) 4+ and tetrahedral (GeS 4 ) 4
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