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Crystal Structures, Electronic Properties, and Pressure-Induced Superconductivity of the Tetrahedral Cluster Compounds GaNb4S8, GaNb4Se8, and GaTa4Se8.

✍ Scribed by Regina Pocha; Dirk Johrendt; Bingfang Ni; Mohsen M. Abd-Elmeguid

Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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New tetrahedral metal cluster compounds were synthesized and characterized by means of single crystal Xray methods. GeV 4 S 8 (F43m, Z = 4, a = 9.655(1) A Ê ) and GeV 4 S 8 (a = 10.139(1) A Ê ) crystallize in the GaMo 4 S 8 -structure, built up by cubane-like (V 4 S 4 ) 4+ and tetrahedral (GeS 4 ) 4

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v