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ChemInform Abstract: Crystal and Electronic Structure of the Tetrahedral V4 Cluster Compounds GeV4Q8 (Q: S, Se).

✍ Scribed by D. JOHRENDT


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Crystal and Electronic Structure of the
✍ Dirk Johrendt πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 German βš– 173 KB πŸ‘ 2 views

New tetrahedral metal cluster compounds were synthesized and characterized by means of single crystal Xray methods. GeV 4 S 8 (F43m, Z = 4, a = 9.655(1) A Ê ) and GeV 4 S 8 (a = 10.139(1) A Ê ) crystallize in the GaMo 4 S 8 -structure, built up by cubane-like (V 4 S 4 ) 4+ and tetrahedral (GeS 4 ) 4