Tetrachlorinated rubber: The addition of carbon tetrachloride to 1,4-polybutadiene
β Scribed by Hadassa Rosin; M. Asscher
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 368 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0021-8995
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## Abstract The Pdβcatalyzed addition of carbon monoxide and carbon tetrachloride to 1βoctene gave coadduct [alkyl 2β(2, 2, 2βtrichloroethyl)octanoate] as the major product in supercritical carbon dioxide by using pyridine as the base. It was found that the selectivity and the yield of coadduct wer
Thus, compound (I) with methylamine gave N,N,N'-trimethylformamidinium methyl sulfate (90 % yield), from which the hitherto unknown, free trimethylformamidine (b.p. 108 "C/740 mm.; ng = 1.4490) can be obtained in good yields. Compound (I) and dimethylamine form N,N,N',N'-tetramethylformamidinium met