𝔖 Bobbio Scriptorium
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Pyrroline by the 1.4-Addition of Imene to Butadiene

✍ Scribed by Prof. Dr. R. Appel; Dr. O. Büchner


Publisher
John Wiley and Sons
Year
1962
Tongue
English
Weight
240 KB
Volume
1
Category
Article
ISSN
0044-8249

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✦ Synopsis


Thus, compound (I) with methylamine gave N,N,N'-trimethylformamidinium methyl sulfate (90 % yield), from which the hitherto unknown, free trimethylformamidine (b.p. 108 "C/740 mm.; ng = 1.4490) can be obtained in good yields. Compound (I) and dimethylamine form N,N,N',N'-tetramethylformamidinium methyl sulfate (94 % yield). Using sodium methylate, this compound can be converted in equally good yields into the highly reactive bis(dimethy1amino)methoxymethane (b.p. 128OC; n g = 1.4158), which is an aminal ester [5].


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ChemInform Abstract: Radical Addition of
✍ S. D. BURLAKA; G. F. MUZYCHENKO; V. G. GLUKHOVTSEV; G. I. NIKISHIN; V. G. KULNEV 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

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