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Polymer modification and synthesis using sulphenyl derivatives: 9. Addition of alkylsulphenyl chlorides to cis-1, 4-polybutadiene

✍ Scribed by Gavin M. Buchan; G.Gordon Cameron


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
491 KB
Volume
19
Category
Article
ISSN
0032-3861

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πŸ“œ SIMILAR VOLUMES


Polymer modification and synthesis using
✍ A.T. Bullock; G.G. Cameron; R.B. Mutr πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 208 KB

Dielectric absorption and dispersion has been observed in two adducts of p-toluenesulphenyl chloride (TSCI to eis-l.4-polybutadiene (PBD) viz. the 100') o and 50Β°0 adducts respectively (mole ratios of TSC to monomer of 1 : 1 and 1:2). In the 100Β°o adduct, measurements at 1 kHz over the temperature r

Polymer modification and synthesis using
✍ G.G. Cameron; S.A.A. Chishti; J.R. Ebdon; F. Heatley πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 402 KB

Analysis of the CH--S and CH--CI multiplets in the t3C NMR spectra of modified polymers indicates that the addition of benzenesulphenyl chloride to cis-l,4-polybutadiene is not wholly random. The analysis of the methylene resonances was inconclusive because of peak overlap and other uncertainties.