The title compound, C 12 H 16 BrNO 2 , was synthesized in 95% yield by condensation of 5-bromo-2-methoxybenzaldehyde and N-tert-butyl-hydroxylamine acetate in the presence of triethylamine as the base and anhydrous magnesium sulfate as the dehydrating agent. The C N bond leads to a plane containing
tert-Butyl N-(2-bromocyclohex-2-enyl)-N-(2-furylmethyl)carbamate
✍ Scribed by Koşar, Başak ;Demircan, Aydın ;Karaarslan, Muhsin ;Büyükgüngör, Orhan
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 316 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, C 19 H 28 BrNO 3 , which crystallizes with two molecules in the asymmetric unit, the six-membered cyclohexanone ring exists in a sightly distorted chair conformation. The bromo and methoxyethoxy groups are oriented axially, whereas the phenyl group and tert-butyl adopt equator
Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.002 A Ê R factor = 0.037 wR factor = 0.112 Data-to-parameter ratio = 25.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The six-membered ring in the title compound, C~10~H~17~NO~4~, has a half-chair conformation and lies to one side of the central chromophore. Molecules are connected into a supramolecular chain __via__ N—H...O hydrogen-bonding interactions and these are consolidated into a three-dimensional structure