2-Bromo-N-tert-butyl-N,1-dimethyl-1H-indole-3-carboxamide
✍ Scribed by Badenock, Jeanese C. ;Fraser, Heidi L. ;Gribble, Gordon W. ;Jasinski, Jerry P.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 98 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the title compound, C 19 H 15 BrN 2 O 4 S, the orientations of the phenylsulfonyl and 2-bromo-4,5-dimethoxybenzyl substituents with respect to the indole moiety are influenced by intramolecular C-HÁ Á ÁO and C-HÁ Á ÁBr interactions. The sulfonyl-bound phenyl ring forms a dihedral angle of 86.9 (1
In the title compound, C 23 H 19 Br 2 NO 4 S, the orientation of the phenylsulfonyl substituent with respect to the indole ring system is influenced by intramolecular C-HÁ Á ÁO interactions. The sulfonyl-bound phenyl ring is orthogonal to the indole ring system. In the crystal structure,stacking int
The title compound, C 20 H 21 NO, was obtained by the reaction of indole-3-carbaldehyde with 4-tert-butylbenzyl chloride and recrystallization of the product from ethanol. The indole ring system is nearly planar and makes a dihedral angle of 74.45 (3) with the plane of the 4-tert-butylphenyl ring.
The phenyl ring in the title compound, C~15~H~11~Br~2~NO~2~S, makes a dihedral angle of 81.8 (1)° with the mean plane of the indole system. The molecular structure is stabilized by C—H...O hydrogen bonds.