tert-Butyl N-[1-(3-tert-butyl-2-hydroxyphenyl)-1-hydroxy-3-phenyl-2-propyl]carbamate
✍ Scribed by Bocelli, G. ;Cantoni, A.
- Book ID
- 114506873
- Publisher
- International Union of Crystallography
- Year
- 1990
- Tongue
- English
- Weight
- 197 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0108-2701
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The six-membered ring in the title compound, C~10~H~17~NO~4~, has a half-chair conformation and lies to one side of the central chromophore. Molecules are connected into a supramolecular chain __via__ N—H...O hydrogen-bonding interactions and these are consolidated into a three-dimensional structure
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.050 wR factor = 0.157 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 26 H 24 O, was obtained from the reaction of 2-[(4-tert-butyl)phenylmethyl]-1,3-diphenylpropane-1,3dione with acetic anhydride. The reaction yielded 92% of the product. The crystal structure con®rms the formation of the ®ve-membered ring from the parent dione.