In the title compound, C 20 H 24 , the central cyclohexene ring is in a distorted half-chair conformation. The crystal structure is stabilized by weak van der Waals interactions.
tert-Butyl (2-phenyl-1,2-dihydro-1-naphthyl)carbamate
✍ Scribed by Dockendorff, Chris ;Lautens, Mark ;Lough, Alan J.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 175 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The crystal structure of the title compound, C 23 H 22 O 2 , which exists in the enol form, is stabilized by an intramolecular hydrogen bond. The dihedral angle between the naphthyl ring system and the aromatic ring of the t-BuC 6 H 4 group is 23.50 (10) .
The six-membered ring in the title compound, C~10~H~17~NO~4~, has a half-chair conformation and lies to one side of the central chromophore. Molecules are connected into a supramolecular chain __via__ N—H...O hydrogen-bonding interactions and these are consolidated into a three-dimensional structure
In the title compound, C~23~H~25~N~3~O~3~, all bond lengths and angles show normal values. The dihedral angles between the rings of the pyrazole and the unsubstituted and __tert__-butyl-substituted benzene rings are 8.6 (2) and 78.5 (3)°, respectively, while that between the two benzene rings is 76.