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tert-Butyl (2-phenyl-1,2-dihydro-1-naphth­yl)carbamate

✍ Scribed by Dockendorff, Chris ;Lautens, Mark ;Lough, Alan J.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
175 KB
Volume
62
Category
Article
ISSN
1600-5368

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4-tert-Butyl-1-(1-naphth­yl)cyclo­hexene
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In the title compound, C 20 H 24 , the central cyclohexene ring is in a distorted half-chair conformation. The crystal structure is stabilized by weak van der Waals interactions.

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The crystal structure of the title compound, C 23 H 22 O 2 , which exists in the enol form, is stabilized by an intramolecular hydrogen bond. The dihedral angle between the naphthyl ring system and the aromatic ring of the t-BuC 6 H 4 group is 23.50 (10) .

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The six-membered ring in the title compound, C~10~H~17~NO~4~, has a half-chair conformation and lies to one side of the central chromophore. Molecules are connected into a supramolecular chain __via__ N—H...O hydrogen-bonding interactions and these are consolidated into a three-dimensional structure

2-{5-[N-(4-tert-Butyl­benz­yl)carbamo­yl
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In the title compound, C~23~H~25~N~3~O~3~, all bond lengths and angles show normal values. The dihedral angles between the rings of the pyrazole and the unsubstituted and __tert__-butyl-substituted benzene rings are 8.6 (2) and 78.5 (3)°, respectively, while that between the two benzene rings is 76.