4-tert-Butyl-1-(1-naphthyl)cyclohexene
✍ Scribed by Periasamy, M. ;Soundirapandian, Sudha ;Athimoolam, S. ;Ponnusamy, A. ;Natarajan, S.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 281 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 20 H 24 , the central cyclohexene ring is in a distorted half-chair conformation. The crystal structure is stabilized by weak van der Waals interactions.
📜 SIMILAR VOLUMES
The crystal structure of the title compound, C 23 H 22 O 2 , which exists in the enol form, is stabilized by an intramolecular hydrogen bond. The dihedral angle between the naphthyl ring system and the aromatic ring of the t-BuC 6 H 4 group is 23.50 (10) .
In the title compound, C~21~H~28~N~2~, the two benzene rings are oriented nearly perpendicular to each other, and the piperazine ring adopts a chair conformation.
The title compound, C 20 H 21 NO, was obtained by the reaction of indole-3-carbaldehyde with 4-tert-butylbenzyl chloride and recrystallization of the product from ethanol. The indole ring system is nearly planar and makes a dihedral angle of 74.45 (3) with the plane of the 4-tert-butylphenyl ring.