Terpenes in organic synthesis. 7. Synthesis of (S)-(+)-3-methylheneicosan-2-one from (s)-(+)-3,7-dimethylocta-1,6-diene
✍ Scribed by Nguen Kong Khao; M. V. Mavrov; É. P. Serebryakov
- Book ID
- 112450187
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 266 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1573-9171
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Total Partial Synthesis of (3S,6S)-(+)-3,7-Dimethyl-6-hydroxy-3acetoxyocta-1,7-diene and (3S,6S)-(-)-3,7-Dimethylocta-1,7-diene-3,6diol from Geraniol. -The asymmetric synthesis of (VI) from geraniol via rearrangement of the chiral 2,3-epoxy alcohols (I) and (V) using the system Ph 3 P, pyridine, I
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