Total Partial Synthesis of (3S,6S)-(+)-3,7-Dimethyl-6-hydroxy-3acetoxyocta-1,7-diene and (3S,6S)-(-)-3,7-Dimethylocta-1,7-diene-3,6diol from Geraniol. -The asymmetric synthesis of (VI) from geraniol via rearrangement of the chiral 2,3-epoxy alcohols (I) and (V) using the system Ph 3 P, pyridine, I
ChemInform Abstract: Synthesis of Derivatives of (S)-2-Alkanols, Components of Pheromones of Drosophila mulleri and Rhyzopertha dominica, from (S)-(+)-3,7-Dimethylocta-1,6-diene.
β Scribed by G. Yu. Ishmuratov; R. Ya. Kharisov; O. V. Botsman; V. V. Zorin; G. A. Tolstikov
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 31 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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Abstract
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Pheromone Synthesis. Part 183. Synthesis of (1R,2R,5S,7R)-and (1R,2S, 5S,7R)-2-Hydroxy-exo-brevicomin, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle, Dendroctonus ponderosae. -Both title compounds (V) and (VI) are synthesized via asymmetric dihydroxylation as the key ste