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ChemInform Abstract: Total Partial Synthesis of (3S,6S)-(+)-3,7-Dimethyl-6-hydroxy-3-acetoxyocta-1,7-diene and (3S,6S)-(-)-3,7-Dimethylocta-1,7-diene-3,6-diol from Geraniol.

✍ Scribed by Zuosheng Liu; Jiong Lan; Yulin Li; Yacheng Xing; Wen Cen

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Total Partial Synthesis of (3S,6S)-(+)-3,7-Dimethyl-6-hydroxy-3acetoxyocta-1,7-diene and (3S,6S)-(-)-3,7-Dimethylocta-1,7-diene-3,6diol from Geraniol.

-The asymmetric synthesis of (VI) from geraniol via rearrangement of the chiral 2,3-epoxy alcohols (I) and (V) using the system Ph 3 P, pyridine, I 2 , and H 2 O, respectively, is described. -(LIU, ZUOSHENG;

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