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ChemInform Abstract: New Preparation of (3aR*,6S*,7aR*)-6,7,7-trimethylhexahydro-2-benzofuran-1(3H)-one: Formal Synthesis of (.+-.)-γ-Irone.

✍ Scribed by Pascal Gosselin; Angelique Perrotin; Stephane Mille

Publisher
John Wiley and Sons
Year
2001
Weight
34 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of (1R,2R,3R,7R,7aR)-Hexahydro-3- (hydroxymethyl)-1H-pyrrolizine-1,2,7-triol: 7-Epiaustraline.
✍ S. E. DENMARK; B. HERBERT 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Synthesis of (1R,2R,3R,7R,7aR)-Hexahydro-3-(hydroxymethyl)-1Hpyrrolizine-1,2,7-triol: 7-Epiaustraline. -Title compound (VI) is synthesized from known nitronate (I), prepared via [4 + 2] cycloaddition, in order to establish [4 + 2]/[3 + 2] cycloaddition chemistry as a general strategy for the synthe